Preparation of 4-sulfonylcalix[6]arene modified Fe3O4 as adsorbent for adsorption of U(VI) from aqueous solution

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作者信息关键词期刊信息基础信息归属信息摘要

成果类型：

期刊论文

作者：

Liao, Qi;Li, Le*;Yuan, Yali*;Cheng, Bin;Lu, Wei;...

通讯作者：

Li, Le;Yuan, Yali

作者机构：

[Cheng, Bin; Lu, Wei; Li, Le; Liao, Qi] Univ South China, Key Discipline Lab Natl Def Biotechnol Uranium Mi, Hengyang 421001, Peoples R China.

[Hou, Shaoyan; Yuan, Yali; Liao, Qi] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.

[Cheng, Bin; Lu, Wei; Li, Le] Univ South China, Sch Publ Hlth, Hengyang 421001, Peoples R China.

通讯机构：

[Li, Le; Yuan, Yali] U

Univ South China, Key Discipline Lab Natl Def Biotechnol Uranium Mi, Hengyang 421001, Peoples R China.

Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.

Univ South China, Sch Publ Hlth, Hengyang 421001, Peoples R China.

语种：

英文

关键词：

4-Sulfonylcalix[6]arene;Fe3O4;Co-precipitation;Adsorption;Uranium

期刊：

Journal of Radioanalytical and Nuclear Chemistry

ISSN：

0236-5731

年：

2018

卷：

315

期：

页码：

251-261

DOI：

10.1007/s10967-017-5650-y

基金类别：

National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [11405081]; Natural Science Foundation of Hunan ProvinceNatural Science Foundation of Hunan Province [2017JJ3276]; Department of Education of Hunan Province [17B226]; Department of Environmental Protection of Hunan Province [2016-59-23]; Hunan Provincial Department of Environmental Protection Research Project [59]

机构署名：

本校为第一且通讯机构

院系归属：

化学化工学院

核资源工程学院

公共卫生学院

摘要：

The 4-sulfonylcalix[6]arene modified Fe 3 O 4 (MFS) was characterized by FT-IR, SEM, VSM, TGA, etc., which showed that its saturation magnetization was 64.99 emu g −1 with the particle size 10–40 nm. The maximum adsorption efficiency by MFS for 2.5 mg L −1 U(VI) solution amounted to 94.39%, which was higher than that by Fe 3 O 4 (65.22%) under its optimum adsorption conditions. The adsorption of MFS and Fe 3 O 4 were both followed the pseudo-second order model and the Langmuir isotherm model. The Gibbs free energy change and enthalpy change ...

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Preparation of 4-sulfonylcalix[6]arene modified Fe3O4 as adsorbent for adsorption of U(VI) from aqueous solution

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