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Magnetic Properties and Mossbauer Investigation of LaFe0.75Cr0.25O3 Perovskite

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成果类型:
期刊论文
作者:
Xia, Puyue;Mo, Jiajun;Lu, Zeyi;Zhang, Qinghang;Chen, Yan;...
通讯作者:
Min Liu
作者机构:
[Zhang, Qinghang; Wang, Xinyu; Liu, Min; Mo, Jiajun; Lu, Zeyi; Chen, Yan; Xia, Puyue] Univ South China, Coll Nucl Sci & Technol, Hengyang 421001, Peoples R China.
通讯机构:
[Min Liu] C
College of Nuclear Science and Technology, University of South China, Hengyang, China
语种:
英文
关键词:
Cr-doped LaFeO3;Mössbauer spectroscopy;Crystal structure
期刊:
Journal of Superconductivity and Novel Magnetism
ISSN:
1557-1939
年:
2022
卷:
35
期:
11
页码:
3271-3275
基金类别:
This research was supported partly by the National Undergraduate Innovation and Entrepreneurship Training Program Support Projects of China (Grant No. 20200112), the Natural Science Foundation of Hunan Province, China (Grant No. 2020JJ4517), Research Foundation of Education Bureau of Hunan Province, China (Grant No. 19C1621, 19A434), and National Natural Science Foundation of China (Grant No. 12105137).
机构署名:
本校为第一机构
院系归属:
核科学技术学院
摘要:
In this paper, LaFe0.75Cr0.25O3 was synthesized by a citric acid combusting sol-gel method. The basic structural information is reflected by XRD. According to Mossbauer spectroscopy, the inhomogeneous distribution of Cr contributes to magnetic dilution, thus appearing the coexistence of singlet and sextet. Simultaneously, the rare superparamagnetic relaxation appears due to "critical superparamagnetism" caused by small magnetic clusters with intervening sizes. Oxygen vacancies of synthesized sample are also found. The DC magnetization curve reveals the magnetization reversal phenomenon, which ...

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