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Electro-oxidation of Ni (II)-citrate complexes at BDD electrode and simultaneous recovery of metallic nickel by electrodeposition

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成果类型:
期刊论文
作者:
Zhuo, Qiongfang;Xu, Xiaofeng;Xie, Shuibo;Ren, Xiuwen;Chen, Zhongying;...
通讯作者:
Xie, SB
作者机构:
[Zhuo, Qiongfang; Xu, Xiaofeng; Niu, Junfeng; Li, Yanliang] Dongguan Univ Technol, Sch Environm & Civil Engn, Dongguan 523808, Peoples R China.
[Xie, Shuibo; Xu, Xiaofeng] Univ South China, Sch Civil Engn, Hengyang 421001, Peoples R China.
[Chen, Zhongying; Ren, Xiuwen] MEE, South China Inst Environm Sci, Guangzhou 510655, Peoples R China.
[Yang, Bo] Shenzhen Univ, Coll Chem & Environm Engn, Shenzhen 518071, Peoples R China.
通讯机构:
[Xie, SB ] U
Univ South China, Sch Civil Engn, Hengyang 421001, Peoples R China.
语种:
英文
关键词:
Electrochemical oxidation;Electrodeposition;BDD anode;Metal complexes;Metallic nickel recovery
期刊:
环境科学学报(英文版)
ISSN:
1001-0742
年:
2022
卷:
116
期:
6
页码:
103-113
基金类别:
Major Science and Technology Program for Water Pollution Control and Treatment in China [2017ZX07202-001-007]; National Science Fund for Distinguished Young ScholarsNational Natural Science Foundation of China (NSFC)National Science Fund for Distinguished Young Scholars [51625801]; Guangdong Innovation Team Project for Colleges and Universities [2016KCXTD023]; Guangdong Provincial Science and Technology Project [2017A020216014]; National Science Fund, China [21777106]; Pearl River S&T Noval Program of Guangzhou, China [201710010065]; key projects of Dongguan social science and technology development plan [2019507140204]
机构署名:
本校为通讯机构
院系归属:
土木工程学院
摘要:
The simultaneous electro-oxidation of Ni (II)-citrate and electrodeposition recovery of nickel metal were attempted in a combined electro-oxidation-electrodeposition reactor with a boron-doped diamond (BDD) anode and a polished titanium cathode. Effects of initial nickel citrate concentration, current density, initial pH, electrode spacing, electrolyte type, and initial electrolyte dosage on electrochemical performance were examined. The efficiencies of Ni (II)-citrate removal and nickel metal recovery were determined to be 100% and over 72%, respectively, under the optimized conditions (10 mA...

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