National Natural Science Foundation of ChinaNational Natural Science Foundation of China [21971261]; ``Double First-Class'' Discipline Construction Foundation of the University of South China [2017SYL06]; Foundation of Hu'nan Educational Committee [18C0476]
机构署名：
本校为第一且通讯机构
院系归属：
药学与生物科学学院
摘要：
The synthesis of α-boryl halohydrins via difunctionalization of alkenyl MIDA boronates has been reported. Intriguing stereoselectivity was found with different halogen sources, which arises from the special stabilizing effect of the B(MIDA) moiety. The transformation provided cis addition products using Cl+ or Br+ as the halogen source, while trans addition products were obtained when I+ was employed. ...
