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Tetraphenylimidodiphosphinate as solid phase extractant for preconcentrative separation of thorium from aqueous solution

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成果类型:
期刊论文
作者:
Liu, Na;Wang, Yanfei*;He, Chuhua
通讯作者:
Wang, Yanfei
作者机构:
[He, Chuhua; Liu, Na; Wang, Yanfei] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Hunan, Peoples R China.
通讯机构:
[Wang, Yanfei] U
Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Hunan, Peoples R China.
语种:
英文
关键词:
Tetraphenylimidodiphosphinate (Htpip);Thorium;Solid phase extraction;Extraction efficiency
期刊:
Journal of Radioanalytical and Nuclear Chemistry
ISSN:
0236-5731
年:
2016
卷:
308
期:
2
页码:
393-401
机构署名:
本校为第一且通讯机构
院系归属:
化学化工学院
摘要:
A simple and reliable method for solid phase extraction of thorium using tetraphenylimidodiphosphinate is presented. The solid phase extraction process was optimized at equilibrium time 3 h, pH = 4.5, initial concentration 30 mg L−1 and extractant dosage 0.01 g with 98.95 % of removal efficiency and 29.68 mg g−1 of adsorption capacity. The interfering ions experiments indicated that it had almost no effect on thorium adsorption. Kinetics data follow the pseudo-first-order model and equilibrium data agreed with the Langmuir isotherm model very...

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