In the development of metal-organic frameworks (MOFs), expansion of pore size and exploration of facile preparation conditions are considered as two major goals that are rarely realized together. This study develops a facile method for the room-Temperature synthesis of hierarchically porous MIL-100(Fe) under HF-free conditions using a mixed-ligand strategy by simultaneously introducing p-benzoquinone and terephthalic acid (TPA). The resulting MIL-100(Fe) products exhibited abundant micropores, large mesopores (â 40 nm) and macropores, and high...
