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Assay of 1-hydroxypyrene via aggregation-induced quenching of the fluorescence of protamine-modified gold nanoclusters and 9-hydroxyphenanthrene-based sensitization.

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成果类型:
期刊论文
作者:
Xue, Jin-Hua;Liu, Ling;Wang, Yong-Sheng*;Li, Jia-Qian;Li, Mei;...
通讯作者:
Wang, Yong-Sheng;Li, Le
作者机构:
[Li, Jia-Qian; Li, Mei; Qu, Yue-Ning; Liu, Ling; Li, Le; Wang, Yong-Sheng; Xue, Jin-Hua] Univ South China, Coll Publ Hlth, Hengyang 421001, Peoples R China.
通讯机构:
[Wang, YS; Li, L] U
Univ South China, Coll Publ Hlth, Hengyang 421001, Peoples R China.
语种:
英文
关键词:
Nanoprobe;Photoluminescence quenching;High quantum efficiency;Electrostatic interactions;Hydrogen bonding;Hydrophobic interaction;Resonance energy transfer;Human urine samples
期刊:
Microchimica Acta
ISSN:
0026-3672
年:
2019
卷:
186
期:
11
页码:
700
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21177052, 11405081]; Science and Technology Program of Hunan Province in China [2010SK3039]; Key R&D Program of Hunan Province [2018SK2029]; Fund of Hengyang Key Laboratory [2018KJ110]; Research Study and Innovation Experiment Program for University Students [477]
机构署名:
本校为第一且通讯机构
院系归属:
公共卫生学院
摘要:
This work describes a method for the determination of 1-hydroxypyrene (OH-Py) via aggregation-induced quenching of the emission of protamine-coated gold nanoclusters using 9-hydroxyphenanthrene (OH-Phe) as a sensitizer to boost the emission efficiency of nanoprobe. Under optimum conditions, the drop in fluorescence intensity at excitation/emission wavelengths of 300/596 nm is proportional to the concentrations of OH-Py in the range from 1.0 to 65 nM. The relative standard deviations are 4.2, 2.4 and 1.9% (for n = 11) at concentration levels of 8.0, 32 and 48 nM of OH-Py, respectively. The dete...

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