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Highly Efficient Removal of Uranium(VI) From Aqueous Solution Using the Polyethyleneimine Modified Magnetic Chitosan

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成果类型:
期刊论文
作者:
Wang, Zhihui;Wang, Yanfei;Yao, Chen
通讯作者:
Yanfei Wang
作者机构:
[Wang, Zhihui; Yao, Chen; Wang, Yanfei] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.
通讯机构:
[Yanfei Wang] S
School of Chemistry and Chemical Engineering, University of South China, Hengyang, People’s Republic of China
语种:
英文
关键词:
Chemicals removal (water treatment);Chitosan;Crosslinking;Iron oxides;Magnetism;Magnetite;Sodium compounds;Uranium compounds;Adsorption capacities;Cross linking agents;Dubinin-Radushkevich;Environmental-friendly;Pseudo-second order model;Single-factor experiments;Sodium polyphosphate;Thermodynamic studies;Adsorption;adsorption;aqueous solution;concentration (composition);experimental study;polymer;uranium
期刊:
Journal of Polymers and the Environment
ISSN:
1566-2543
年:
2022
卷:
30
期:
3
页码:
855-866
基金类别:
This work was supported by the National Natural Science Foundation of China [51803088]; the Natural Science Foundation of Hunan Province, China [2020JJ5493]; and the Scientific Research Fund of Hunan Education Department [17C1360].
机构署名:
本校为第一机构
院系归属:
化学化工学院
摘要:
In this study, Polyethyleneimine modified magnetic chitosan (MCS-PEI) was synthesized by grafting polyethyleneimine onto chitosan and adding magnetic Fe3O4 with sodium polyphosphate as crosslinking agent. The structure of the prepared material was characterized by FT-IR, SEM, EDS, XRD and XPS, which showed MCS-PEI was successfully synthesized. After a series of single factor experiments, the adsorption data fitted well with the Langmuir model (R2 = 0.99), being the maximum adsorption capacity equal 181.8mg g−1. The pseudo-second-order model (R...

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