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Highly efficient removal of uranium(VI) from aqueous solution using poly(cyclotriphosphazene-co-polyethyleneimine) microspheres

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成果类型:
期刊论文
作者:
Xie, Xiaoqing;Wang, Yanfei*;Xiong, Zeng;Li, Hongzheng;Yao, Chen
通讯作者:
Wang, Yanfei
作者机构:
[Xiong, Zeng; Yao, Chen; Xie, Xiaoqing; Li, Hongzheng; Wang, Yanfei] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.
通讯机构:
[Wang, Yanfei] U
Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.
语种:
英文
关键词:
Poly(cyclotriphosphazene-co-polyethyleneimine);Microspheres;Uranium(VI);Adsorption
期刊:
Journal of Radioanalytical and Nuclear Chemistry
ISSN:
0236-5731
年:
2020
卷:
326
期:
3
页码:
1867-1877
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [51803088]; Scientific Research Fund of Hunan Education Department [17C1360]
机构署名:
本校为第一且通讯机构
院系归属:
化学化工学院
摘要:
Poly(cyclotriphosphazene-co-polyethyleneimine) microspheres with the solid structure were synthesized by precipitation polymerization method for the separation of highly toxic uranium(VI). The structure and morphology of the prepared microspheres were analyzed via FTIR, SEM-EDS, TEM and BET. The optimal adsorption conditions were also investigated, and the maximum adsorption capacity was 274.2 mg g(-1). The experimental results showed that the adsorption kinetics conformed to the pseudo-second-order kinetics and was in good agreement with the Langmuir adsorption isotherm model. Removal of uran...

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