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Highly efficient removal of uranium(VI) from aqueous solution using poly(cyclotriphosphazene-co-polyethyleneimine) microspheres

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成果类型:
期刊论文
作者:
Xie, Xiaoqing;Wang, Yanfei*;Xiong, Zeng;Li, Hongzheng;Yao, Chen
通讯作者:
Wang, Yanfei
作者机构:
[Xiong, Zeng; Yao, Chen; Xie, Xiaoqing; Li, Hongzheng; Wang, Yanfei] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.
通讯机构:
[Wang, Yanfei] U
Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.
语种:
英文
关键词:
microsphere;poly(cyclotriphosphazene co polyethyleneimine)microsphere;unclassified drug;uranium;adsorption;aqueous solution;Article;chemical structure;complex formation;energy dispersive X ray spectroscopy;Fourier transform infrared spectroscopy;pH;polymerization;precipitation;scanning electron microscopy;separation technique;surface property;synthesis;thermodynamics;transmission electron microscopy
期刊:
Journal of Radioanalytical and Nuclear Chemistry
ISSN:
0236-5731
年:
2020
卷:
326
期:
3
页码:
1867-1877
基金类别:
The authors gratefully acknowledge support from the National Natural Science Foundation of China (51803088), Scientific Research Fund of Hunan Education Department (17C1360). The authors gratefully acknowledge support from the National Natural Science Foundation of China (51803088), Scientific Research Fund of Hunan Education Department (17C1360).
机构署名:
本校为第一且通讯机构
院系归属:
化学化工学院
摘要:
Poly(cyclotriphosphazene-co-polyethyleneimine) microspheres with the solid structure were synthesized by precipitation polymerization method for the separation of highly toxic uranium(VI). The structure and morphology of the prepared microspheres were analyzed via FTIR, SEM–EDS, TEM and BET. The optimal adsorption conditions were also investigated, and the maximum adsorption capacity was 274.2mgg−1. The experimental results showed that the adsorption kinetics conformed to the pseudo-second-order kinetics and was in good agreement with the Lan...

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