Effect of phosphoric acid additive on the electrolyte of all-vanadium flow batteries

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成果类型：

期刊论文

作者：

Wu, Xuewen;Liao, Jingjing;Yin, Xingrong;Liu, Jun;Wu, Saixiang;...

通讯作者：

Xie, ZY;Wu, XW;Liao, JJ;Wu, Xiongwei;Ling, W

作者机构：

[Wu, Xuewen; Xie, Zhiyong] Cent South Univ, State Key Lab Powder Met, Changsha 410083, Peoples R China.

[Wu, Xuewen; Xie, Zhiyong] Cent South Univ, Sci & Technol High Strength Struct Mat Lab, Changsha 410083, Peoples R China.

[Wu, Xiongwei; Wu, Xuewen; Wu, Saixiang; Wu, XW; Yin, Xingrong; Liu, Jun] Hunan Prov YinFeng New Energy Co Ltd, Changsha 410000, Peoples R China.

[Liao, Jingjing] Univ South China, Sch Nucl Sci & Technol, Hengyang 421001, Peoples R China.

[Wu, Xiongwei; Ling, Wei; Wu, XW; Ling, W; Liu, Jun] Hunan Agr Univ, Sch Chem & Mat Sci, Changsha 410128, Peoples R China.

通讯机构：

[Xie, ZY ] C

[Wu, XW; Wu, XW ; Ling, W ] H

[Liao, JJ ] U

Cent South Univ, State Key Lab Powder Met, Changsha 410083, Peoples R China.

Cent South Univ, Sci & Technol High Strength Struct Mat Lab, Changsha 410083, Peoples R China.

语种：

英文

期刊：

Chemical Communications

ISSN：

1359-7345

年：

2024

卷：

期：

页码：

2906-2909

DOI：

10.1039/d3cc06298h

基金类别：

Department of Science and Technology of Hunan Province [2021GK5002]; Excellent Youth Program of the Education Department of Hunan Province [23B0221]; High-efficiency recovery and high-value utilization of vanadium and titanium from vanadium and titanium magnetite [2023YFC2908300]

机构署名：

本校为通讯机构

院系归属：

核科学技术学院

摘要：

A phosphoric acid additive with an optimal concentration of 0.1 M can vastly promote the diffusion kinetics of the redox reaction between V(iv) and V(v) without a significant decline in energy efficiency for 300 cycles, and maintain the high-temperature stability (55 degrees C) of an electrolyte at a high state of charge (SOC) of 70% over the course of 30 days. A phosphoric acid additive with an optimal concentration of 0.1 M can maintain the high-temperature stability (55 degrees C) of an electrolyte at a h...

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Effect of phosphoric acid additive on the electrolyte of all-vanadium flow batteries

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