Revisiting the Theory of Coagulation of Colloidal Dispersions: An Improved Expression for the Stability Ratio

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成果类型：

期刊论文

作者：

Liu, Longcheng*;Meng, Shuo;Li, Chunguang;Li, Yongmei*

通讯作者：

Li, Yongmei;Liu, Longcheng

作者机构：

[Liu, Longcheng] China Inst Atom Energy, Dept Radiochem, Beijing 102413, Peoples R China.

[Meng, Shuo] Univ South China, Sch Nucl Sci & Technol, Hengyang 421001, Peoples R China.

[Li, Yongmei; Li, YM; Meng, Shuo; Li, Chunguang] Univ South China, R&D & Modelling Ctr Treatment & Disposal Radioact, Hengyang 421001, Peoples R China.

[Li, Yongmei; Li, YM; Li, Chunguang] Univ South China, Sch Resource Environm & Safety Engn, Hengyang 421001, Peoples R China.

[Liu, Longcheng] KTH Royal Inst Technol, Dept Chem Engn, S-10044 Stockholm, Sweden.

通讯机构：

[Li, Yongmei] U

[Liu, Longcheng] C

[Liu, Longcheng] K

Univ South China, R&D & Modelling Ctr Treatment & Disposal Radioact, Hengyang 421001, Peoples R China.

Univ South China, Sch Resource Environm & Safety Engn, Hengyang 421001, Peoples R China.

语种：

英文

期刊：

LANGMUIR

ISSN：

0743-7463

年：

2022

卷：

期：

页码：

1131-1140

DOI：

10.1021/acs.langmuir.1c02790

基金类别：

China Institute of Atomic Energy (CIAE); University of South China (USC); Natural Science Foundation of Hunan ProvinceNatural Science Foundation of Hunan Province [2019JJ50496]; Research Foundation of Education Bureau of Hunan Province [18C0460, 20B494]

机构署名：

本校为通讯机构

院系归属：

核科学技术学院

摘要：

The stability of a colloidal dispersion has long been expressed in terms of the stability ratio. Based on the available theories of coagulation of colloidal dispersions, a novel expression, complying with the classical definition, is developed for the stability ratio. It accounts for the contributions of both primary and secondary minimum coagulations to the overall rate of coagulations. In addition, it can also be regarded as the result of a combination of the kinetic theory of an ideal gas and the Smoluchowski theory with Fuchs' correction, considering the interaction between identical spher...

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Revisiting the Theory of Coagulation of Colloidal Dispersions: An Improved Expression for the Stability Ratio

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