Cyclo crosslinked polyphosphazenes (PPNs) were prepared by Hexachlorocyclotriphosphazene (HCCP) with unique P = n structure and active p-cl group and green compound phloretin. The synthesis pro cess of polyphosphazene nanospheres with Hexachlorocyclotriphosphazene as the main body and phloretin was discussed. The effects of pH value and solid-liquid ratio of solution on the adsorption of uranium by pol yphosphazene nanospheres were studied. The results show that polyphosphazene nanospheres are off white powder in appearance and spherical in mic...