期刊论文

Photo‐/electrocatalytic functionalization of quinoxalin‐2(1H)‐ones

Yu, Bing(bingyu@zzu.edu.cn);He, Wei-Min(weiminhe2016@yeah.net)

英文

催化学报

0253-9837

2021

42

11

1921-1943

10.1016/S1872-2067(21)63850-0

Natural Science Foundation of Henan Province [202300410375]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21971224]; Henan Postdoctoral Foundation [202003014]; Hunan Provincial Natural Science Foundation of ChinaNatural Science Foundation of Hunan Province [2019JJ40090]

本校为其他机构

The photo-/electrocatalytic functionalization of quinoxalin-2(1H)-ones has emerged as a promising and powerful approach for post-synthetic modification of quinoxalin-2(1H)-ones. This review provides an overview of recent developments in photo-/electrocatalytic functionalization of quinoxalin-2(1H)-ones including arylation, alkylation, fluoroalkylation, amination, phosphorylation, acylation, alkoxylation, thiolation, silylation, and annulation. The reaction scope and the related mechanism are also well discussed. © 2021 Dalian In...

喹喔啉酮作为重要的含氮杂环骨架,广泛应用于抗菌化合物、抗肿瘤药物、半导体材料中.因此,开发新方法合成不同官能团化喹喔啉酮以丰富其结构多样性在近年来广受关注.在众多合成方法中,喹喔啉酮的直接C–H官能团化是一类步骤经济性较高、简便高效地构建喹喔啉酮衍生物的重要方法.近年来,光催化、电催化和光电催化技术已发展成为现代有机合成中强有力的绿色合成工具,可以有效利用光能或者电能促进有机化学转化,减少传统有机反应中的高能耗.过去几年,化学工作者在光/电催化喹喔啉酮的直接C–H官能团化反应方面进行了大量研究,开发了系列不同官能团化喹喔啉酮的绿色合成方法.本文系统总结了喹喔啉酮...