Early transition metals based 2D carbides, nitrides and carbonitrides nanomaterials are known as MXenes, a novel and extensive new class of 2D‐materials family. Due to its distinctive surface chemistry, graphene like shape, metallic conductivity, high hydrophilicity, outstanding mechanical and thermal properties, redox capacity and affordable with mass‐produced nature, this diverse MXenes are of tremendous scientific and technological significance. Abstract Early transition metals based 2D carbides, nitrides and carbonitrides nanomaterials ar...