期刊论文、会议论文

Luo, Cai-Wu

英文

IOP Conference Series: Earth and Environmental Science

1755-1307

2017

94

1

2017 3rd International Conference on Energy, Environment and Materials Science (EEMS)

IOP Conference Series-Earth and Environmental Science

JUL 28-30, 2017

Northwestern Polytechnical University, Singapore, SINGAPORE

Northwestern Polytechnical University

Northwestern Polytechnical Univ, Nanyang Technological Univ

Wang, H

DIRAC HOUSE, TEMPLE BACK, BRISTOL BS1 6BE, ENGLAND

IOP PUBLISHING LTD

10.1088/1755-1315/94/1/012031

Educational Commission of Hunan Province [17C1361]; Doctoral Scientific Research Foundation of University of South China [2016XQD36]

本校为第一且通讯机构

The liquid-phase synthesis of 3-picoline from the reaction of acrolein diethyl acetal and ammonia over ion-exchanged resins (D402 and D002) and HZSM-5 (Si/Al = 25) was carried out in a batch reactor. Various influencing parameters, including by the addition of water, ion-exchanged resins, reaction temperature and HZSM-5, were systematically investigated. The results showed that the reaction could be directly conducted, and organic acid wasn't utilized. The highest yield of 3-picoline reached up to 24% using HZSM-5 as catalyst at...