期刊论文

Nie, Chang-Ming;Peng, GW

英文

Journal of Molecular Liquids

0167-7322

2024

397

124124

10.1016/j.molliq.2024.124124

CRediT authorship contribution statement Wen-Jun Ouyang: Conceptualization, Formal analysis, Investigation, Methodology, Visualization, Writing – original draft. Meng-Zhen Guo: Investigation, Methodology, Validation. Yun Wang: Conceptualization, Validation. Xiang-He Kong: Data curation. Xi-Lin Xiao: Supervision. Chang-Ming Nie: Conceptualization, acquisition, Resources, Supervision, Writing – review & editing. Guo-Wen Peng: acquisition, Resources.

本校为第一且通讯机构

There are the similar physical and chemical properties between the trivalent actinides (An(III)) and the lan-thanides (Ln(III)), which makes the separation process very difficult for nuclear waste reprocessing. Designing efficient ligands with the strong ability to separate An(III)/Ln(III) is one of the ways to solve the problem, and various ligands with 1,10-Phenanthroline as the skeleton have become a hotspot in recent years. Herein we designed a series of novel ligands using (1,10-phenanthroline-2,9-diyl)bis(indolin-1-ylmethanones)(IDL- DAPhen) as a new skeleton. Using scalar relativistic d...