As an energy-saving and facile technology, the potential of capacitive deionization (CDI) starts to surface in enrichment and recovery of uranium (U(VI)) from aqueous solutions. However, co-ion expulsion effect and poor surface wettability of electrode materials limit the eletrosorption performance. Here, polysaccharides xanthan gum (XG)- and chitosan (CS) -bound porous reduced graphene (RGH) electrodes were rationally designed, and then assembled into asymmetrical electrode configuration for U(VI) eletrosorption. Owing to the introduction of p...