Hunan Provincial Key Laboratory of Pollution Control and Resources Technology, University of South China, Hengyang, People’s Republic of China<&wdkj&>Key Discipline Laboratory for National Defense for Biotechnology in Uranium Mining and Hydrometallurgy, University of South China, Hengyang, People’s Republic of China
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [11475080, 51904155]; Education Department Fund of Hunan Province of China [19C1588]; Natural Science Foundation of Hunan ProvinceNatural Science Foundation of Hunan Province [2020JJ5492]
机构署名:
本校为第一机构
院系归属:
土木工程学院
核资源工程学院
摘要:
The adsorption performance and mechanism of the amino-modified zirconium-based metal organic framework (UiO-66-NH2) for the removal of U(VI) in aqueous solution were studied. Compared with UiO-66, UiO-66-NH2 shows better adsorption performance due to the introduction of amino groups. The adsorption characteristics of factors such as pH, UiO-66-NH2 dosage and contact time were investigated. The results show that the maximum adsorption capacity is 384.6 mg g(-1) at pH = 6 and T = 313 K. The adsorption conforms to the quasi-second-order kinetic model and the Langmuir isotherm model. The thermodyn...