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Performance and mechanism for U(VI) adsorption in aqueous solutions with amino-modified UiO-66

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成果类型:
期刊论文
作者:
Li, Shiyou;Jin, Yuanyuan;Hu, Zhongqing;Liu, Ying;Wu, Suiyi;...
通讯作者:
Guohua Wang
作者机构:
[Liu, Ying; Wang, Yue; Hu, Zhongqing; Wu, Suiyi; Jin, Yuanyuan; Li, Shiyou; Wang, Guohua] Univ South China, Hunan Prov Key Lab Pollut Control & Resources Tec, Hengyang 421001, Peoples R China.
[Li, Shiyou; Wang, Guohua] Univ South China, Key Discipline Lab Natl Def Biotechnol Uranium Mi, Hengyang 421001, Hunan, Peoples R China.
通讯机构:
[Guohua Wang] H
Hunan Provincial Key Laboratory of Pollution Control and Resources Technology, University of South China, Hengyang, People’s Republic of China<&wdkj&>Key Discipline Laboratory for National Defense for Biotechnology in Uranium Mining and Hydrometallurgy, University of South China, Hengyang, People’s Republic of China
语种:
英文
关键词:
Amino-modified metal–organic framework (UiO-66-NH2);Uranium;Characterization;Adsorption performance;Adsorption mechanism
期刊:
Journal of Radioanalytical and Nuclear Chemistry
ISSN:
0236-5731
年:
2021
卷:
330
期:
3
页码:
857-869
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [11475080, 51904155]; Education Department Fund of Hunan Province of China [19C1588]; Natural Science Foundation of Hunan ProvinceNatural Science Foundation of Hunan Province [2020JJ5492]
机构署名:
本校为第一机构
院系归属:
土木工程学院
核资源工程学院
摘要:
The adsorption performance and mechanism of the amino-modified zirconium-based metal organic framework (UiO-66-NH2) for the removal of U(VI) in aqueous solution were studied. Compared with UiO-66, UiO-66-NH2 shows better adsorption performance due to the introduction of amino groups. The adsorption characteristics of factors such as pH, UiO-66-NH2 dosage and contact time were investigated. The results show that the maximum adsorption capacity is 384.6 mg g(-1) at pH = 6 and T = 313 K. The adsorption conforms to the quasi-second-order kinetic model and the Langmuir isotherm model. The thermodyn...

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