Synthesis, structure, and in vitro antiproliferative activity of cyclic hypervalent organobismuth(III) chlorides and their triphenylgermylpropionate derivatives

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成果类型：

期刊论文

作者：

Zhang, Xiao-Wen;Xia, Jun;Yan, Hui-Wen;Luo, Sheng-Lian;Yin, Shuang-Feng*;...

通讯作者：

Yin, Shuang-Feng

作者机构：

[Au, Chak-Tong; Yin, Shuang-Feng; Zhang, Xiao-Wen; Xia, Jun; Luo, Sheng-Lian] Hunan Univ, Coll Chem & Chem Engn, Changsha 410082, Peoples R China.

[Zhang, Xiao-Wen] Univ S China, Key Lab Pollut Control & Resource Use Hunan Prov, Hengyang 421001, Peoples R China.

[Yan, Hui-Wen] Cent S Univ, Cell Biol Biosci & Technol Acad, Changsha 410013, Peoples R China.

[Au, Chak-Tong; Wong, Wai-Yeung] Hong Kong Baptist Univ, Dept Chem, Kowloon Tong, Hong Kong, Peoples R China.

[Wong, Wai-Yeung] Hong Kong Baptist Univ, Ctr Adv Luminescene Mat, Kowloon Tong, Hong Kong, Peoples R China.

通讯机构：

[Yin, Shuang-Feng] H

Hunan Univ, Coll Chem & Chem Engn, Changsha 410082, Peoples R China.

语种：

英文

关键词：

Bismuth;Germanium;Hypervalent;Antiproliferative activity

期刊：

Journal of Organometallic Chemistry

ISSN：

0022-328X

年：

2009

卷：

694

期：

页码：

3019-3026

DOI：

10.1016/j.jorganchem.2009.05.003

机构署名：

本校为其他机构

院系归属：

土木工程学院

摘要：

Six compounds of cyclic hypervalent organobismuth(III) chlorides and triphenylgermylpropionates bearing a nitrogen or sulfur atom as intramolecular coordination atom have been synthesized and characterized. The results of single-crystal X-ray analysis reveal that the eight-membered tetrahydroazabismocine rings are highly flexible. The Bi-S or Bi-N bond lengths in the thiabismocine or azabismocine derivatives are dependent on how the substituted groups are acting on the Bi, S or N atom. The replacement of the chlorine atom in azabismocine and thiabismocine with the triphenylgermylpropionic grou...

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Synthesis, structure, and in vitro antiproliferative activity of cyclic hypervalent organobismuth(III) chlorides and their triphenylgermylpropionate derivatives

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