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Synthesis, structure, and in vitro antiproliferative activity of cyclic hypervalent organobismuth(III) chlorides and their triphenylgermylpropionate derivatives

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成果类型:
期刊论文
作者:
Zhang, Xiao-Wen;Xia, Jun;Yan, Hui-Wen;Luo, Sheng-Lian;Yin, Shuang-Feng*;...
通讯作者:
Yin, Shuang-Feng
作者机构:
[Au, Chak-Tong; Yin, Shuang-Feng; Zhang, Xiao-Wen; Xia, Jun; Luo, Sheng-Lian] Hunan Univ, Coll Chem & Chem Engn, Changsha 410082, Peoples R China.
[Zhang, Xiao-Wen] Univ S China, Key Lab Pollut Control & Resource Use Hunan Prov, Hengyang 421001, Peoples R China.
[Yan, Hui-Wen] Cent S Univ, Cell Biol Biosci & Technol Acad, Changsha 410013, Peoples R China.
[Au, Chak-Tong; Wong, Wai-Yeung] Hong Kong Baptist Univ, Dept Chem, Kowloon Tong, Hong Kong, Peoples R China.
[Wong, Wai-Yeung] Hong Kong Baptist Univ, Ctr Adv Luminescene Mat, Kowloon Tong, Hong Kong, Peoples R China.
通讯机构:
[Yin, Shuang-Feng] H
Hunan Univ, Coll Chem & Chem Engn, Changsha 410082, Peoples R China.
语种:
英文
关键词:
Antiproliferative activities;Antiproliferative activity;Chlorine atom;Cis-platin;Cyclohexyl;Electron-donating ability;Gastric carcinoma;Hypervalent;In-vitro;Intramolecular coordination;Nitrogen atom;Phenyl group;Single bond;Single crystal X-ray analysis;Substituted groups;Sulfur atoms;Atoms;Bismuth;Bond length;Chlorine;Chlorine compounds;Coordination reactions;Derivatives;Germanium;Platinum compounds;Sulfur;Synthesis (chemical);Bismuth compounds
期刊:
Journal of Organometallic Chemistry
ISSN:
0022-328X
年:
2009
卷:
694
期:
18
页码:
3019-3026
基金类别:
This project is financially supported by the National Natural Science Foundation of China (20507005) and the National outstanding Youth Foundation of China (E50725825). C.T. Au and W.Y. Wong thank the Hong Kong Baptist University for financial support (FRG/08-09/II-09). C.T. Au thanks the Hunan University for an adjunct professorship. Prof. S.F. Yin thanks Dr. S. Shimada of AIST in Japan for helpful advices.
机构署名:
本校为其他机构
院系归属:
土木工程学院
摘要:
Six compounds of cyclic hypervalent organobismuth(III) chlorides and triphenylgermylpropionates bearing a nitrogen or sulfur atom as intramolecular coordination atom have been synthesized and characterized. The results of single-crystal X-ray analysis reveal that the eight-membered tetrahydroazabismocine rings are highly flexible. The Bi-S or Bi-N bond lengths in the thiabismocine or azabismocine derivatives are dependent on how the substituted groups are acting on the Bi, S or N atom. The replacement of the chlorine atom in azabismocine and th...

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