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Resonance light scattering detection of uranium based on its reaction with a Schiff base containing tetradentate ligand and phosphate groups to form supramolecular polymer

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成果类型:
期刊论文
作者:
Xu, Canhui;Liao, Lifu*;He, Yunfei;Wu, Rurong;Li, Shijun;...
通讯作者:
Liao, Lifu
作者机构:
[Wu, Rurong; Xu, Canhui; Yang, Yanyan; Li, Shijun; Liao, Lifu; He, Yunfei] Univ South China, Coll Chem & Chem Engn, Hengyang 421001, Hunan, Peoples R China.
通讯机构:
[Liao, Lifu] U
Univ South China, Coll Chem & Chem Engn, Hengyang 421001, Hunan, Peoples R China.
语种:
英文
关键词:
Uranium;Resonance light scattering;Supramolecular polymer;Schiff base;Tetradentate ligand;Phosphate group
期刊:
Journal of Radioanalytical and Nuclear Chemistry
ISSN:
0236-5731
年:
2015
卷:
304
期:
3
页码:
1163-1169
基金类别:
National Natural Science Foundation of China (NSFC)National Natural Science Foundation of China (NSFC) [11275091, 11475079]
机构署名:
本校为第一且通讯机构
院系归属:
化学化工学院
摘要:
To develop a new resonance light scattering (RLS) method for uranium(VI) detection, we have studied the reaction of uranyl with N,N′-bis(pyridoxal phosphate)- o-phenylenediamine (BPPP) that is a Schiff base containing a tetradentate ligand and two phosphate groups. BPPP can chelate uranyl and then self-assemble to form a supramolecular polymer, resulting in a production of strong RLS signal. The RLS method was established based on this fact. The linear range is 0.5–25 ng mL−1 with a detection limit of 0.2 ng mL−1. The method is simple and h...

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