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Resonance light scattering for detecting fluoride ions based on the formation of a uranyl coordination supramolecular polymer

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成果类型:
期刊论文
作者:
Shen, Xing;Liao, Lifu*;Chen, Lin;Xu, Canhui;He, Yunfei;...
通讯作者:
Liao, Lifu
作者机构:
[Xu, Canhui; Chen, Lin; Xiao, Xilin; Liao, Lifu; Nie, Changming; Lin, Yingwu; Shen, Xing; He, Yunfei] Univ South China, Coll Chem & Chem Engn, Hengyang 421001, Hunan, Peoples R China.
通讯机构:
[Liao, Lifu] U
Univ South China, Coll Chem & Chem Engn, Hengyang 421001, Hunan, Peoples R China.
语种:
英文
期刊:
ANALYTICAL METHODS
ISSN:
1759-9660
年:
2014
卷:
6
期:
13
页码:
4818-4822
基金类别:
National Natural Science Foundation of China (NSFC)National Natural Science Foundation of China (NSFC) [11275091, 10975069, 11275090]
机构署名:
本校为第一且通讯机构
院系归属:
化学化工学院
摘要:
A resonance light scattering (RLS) method for the detection of fluoride ions in aqueous solution is reported in this paper. Uranyl-bis-salophen (UBS), a binuclear uranyl complex prepared by the reaction of uranyl with a ditopic tetradentate Schiff base ligand bis-salophen, was used for the experiment. It is found that after UBS self-assembled with pyrophosphate to form a uranyl coordination supramolecular polymer (SP), the system produced a strong RLS signal. When fluoride ions coexisted with UBS, the formation of SP was inhibited due to which ...

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