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Conjugated π-Extension of Small Molecular Nonfullerene Acceptor for Efficient Ternary Organic Solar Cells with an Efficiency of 19.10%

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成果类型:
期刊论文
作者:
Luo, Cheng;Xia, Dongdong*;Wu, Jie;Fang, Jie;Xie, Qian;...
通讯作者:
Wan, LY;Xia, Dongdong;Zhao, CW;Jiang, L
作者机构:
[Wan, Liying; Wan, LY; Luo, Cheng] Nanchang Hangkong Univ, Sch Mat Sci & Engn, Nanchang 330063, Peoples R China.
[Xia, Dongdong; Fang, Jie; Zhang, Yuefeng; Zhao, Chaowei; You, Shengyong; Xie, Qian; Xia, DD] Jiangxi Acad Sci, Inst Appl Chem, Nanchang 330096, Peoples R China.
[Li, Weiwei] Beijing Univ Chem Technol, Beijing Adv Innovat Ctr Soft Matter Sci & Engn, Beijing 100029, Peoples R China.
[Li, Weiwei] Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China.
[Jiang, Lang; Jiang, L] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China.
通讯机构:
[Zhao, CW ; Xia, DD] J
[Jiang, L ] C
[Wan, LY ] N
Nanchang Hangkong Univ, Sch Mat Sci & Engn, Nanchang 330063, Peoples R China.
Jiangxi Acad Sci, Inst Appl Chem, Nanchang 330096, Peoples R China.
语种:
英文
期刊:
Energy & Fuels
ISSN:
0887-0624
年:
2025
卷:
39
期:
8
页码:
4030–4037
基金类别:
Education Department of Hunan Province [52163018, 52303235, 22405107]; NSFC [jxsq2023102153, 20232BAB213021, 20243BCE51130]; Jiangxi Provincial Department of Science and Technology [2022YSBG22031, 2022YJC2019, 2022YYB10, 2022YRCS002, 2023YJC1001, 2023YSBG22025]; Jiangxi Academy of Sciences [22B0420]; Education Department of Hunan Province of China; High Level and Skilled Talents Training Project of Jiangxi Province [XJKX24B420]; Hunan Association of Education Researchers
机构署名:
本校为其他机构
院系归属:
化学化工学院
摘要:
In this study, we have successfully incorporated a small molecular acceptor, Y-LC, with conjugated pi-extension as a secondary acceptor in the PM6:BTP-eC9-based organic photovoltaics. The performance of the device was significantly promoted from 18.45% in the binary system of PM6:BTP-eC9 to over 19% in the ternary system with a minimal Y-LC loading. This enhancement in performance can be attributed to the alloy-like structures of acceptors and the optimized active layer morphology, which leads to improved hole and electron mobilities, thereby suppressing charge recombination, and finally resul...

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