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A new Sc-doped La0.5Sr0.5MnO3-δ cathode allows high performance for proton-conducting solid oxide fuel cells

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成果类型:
期刊论文
作者:
Dai, Hailu;Yin, Yanru;Li, Xiaomei;Ma, Chengjian;Chen, Zhengjie;...
通讯作者:
Lei Bi
作者机构:
[Chen, Zhengjie; Dai, Hailu; Hua, Maoyi] Yancheng Inst Technol, Sch Mat Sci & Engn, Yancheng 224051, Peoples R China.
[Bi, Lei; Yin, Yanru] Univ South China, Sch Resource Environm & Safety Engn, Hengyang 421001, Peoples R China.
[Li, Xiaomei] Qingdao Univ, Inst Mat Energy & Environm, Coll Mat Sci & Engn, Ningxia Rd 308, Qingdao 266071, Peoples R China.
[Ma, Chengjian] Yancheng Inst Technol, Analyt & Testing Ctr, Yancheng 224051, Peoples R China.
通讯机构:
[Lei Bi] S
School of Resource Environment and Safety Engineering, University of South China, Hengyang 421001, China
语种:
英文
关键词:

La0.5Sr0.5MnO3-delta

;Sc-doping;Proton-conducting oxides;H-SOFCs
期刊:
Sustainable Materials and Technologies
ISSN:
2214-9937
年:
2022
卷:
32
页码:
e00409
基金类别:
Acknowledgements This work was supported by the National Natural Science Foundation of China (Grant Number:51972183 and 52002347) and the Startup for Talents at University of South China.
机构署名:
本校为其他机构
摘要:
Sc ions are doped at the Mn site in the ABO3-type perovskite La0.5Sr0.5MnO3-δ (LSM), while the investigation from the density functional theory calculations makes the guidance that the doping of Sc into LSM could be beneficial for its application in proton-conducting solid oxide fuel cells (H-SOFCs) with decreased oxygen formation energy and hydration energy as well as improved oxygen reduction reaction ability. The subsequent experimental studies indicate that the Sc-doped LSM (LSMSc) could greatly boost its performance in H-SOFCs, leading to...

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