Two polymers (polyBAUEE and polyBAUP) containing 25- and 20-membered rings are synthesized by the cyclopolymerization of bifunctional monomers 1,2-bis(acryloyloxyethyl-ureidoethoxyl)-ethane (BAUEE) and 1,3-bis(acryloyloxyethylureido)propane (BAUP) and studied for the adsorption of precious metal ions. PolyBAUEE and polyBAUP selectively adsorb Au(III) with the adsorption efficiencies above 99.0% after adsorption equilibrium. PolyBAUEE adsorbed faster than polyBAUP, and the Au(III) adsorption is selective in the presence of nine interfering metal...