期刊论文

Zheng, Xing;Zhang, Xingang

英文

SYNLETT

0936-5214

2018

29

8

1028-1032

10.1055/s-0036-1591944

National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21425208, 21672238, 21332010, 2142002]; Strategic Priority Research Program of the Chinese Academy of SciencesChinese Academy of Sciences [XDB20000000]; Key Project of Hunan Province Science and Technology Department [2016DK2001]; Key Project of Hengyang Science and Technology Department [2017KJ166]; Shanghai Institute of Organic Chemistry, Chinese Academy of SciencesChinese Academy of Sciences

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Bromotrifluoromethane (CF3Br) is a simple, inexpensive and abundant industrial material employed as a trifluoromethylating reagent. However, only limited strategies using CF3Br as a fluorine source are reported. Herein, we describe a visible-light-induced hydrotrifluoromethylation of alkenes and alkynes with CF3Br. The reaction proceeds under mild conditions with good functional group tolerance, providing a new route ...