Sulfide minerals (mainly FeS2) contained in lead-zinc tailings are easy to be acidified in the air. The acidification mechanism is that the tailing sand generates sulfuric acid and sulfate under the catalysis of oxidant, water and oxygen. The acidic liquid generated by the reaction will continue to react with metal oxides to form an insoluble precipitate.In order to reveal the corresponding changes of chemical properties and physical properties of lead-zinc tailing sand during acidification, a series of reaction processes of tailings under natu...