Halogen-induced core structural evolution of four dinuclear copper(I) luminescent coordination compounds

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成果类型：

期刊论文

作者：

Li, Na;Tan, Chunhong;Feng, Yi;Cheng, Lu;Cao, Meng;...

通讯作者：

Wang, X.-F.;Tan, C.;Sun, Y.

作者机构：

[Feng, Yi; Li, Na; Cheng, Lu; Cao, Meng; Wang, Xiao-Feng; Tan, Chunhong] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Hunan, Peoples R China.

[Tan, Chunhong] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China.

[Sun, Yunkai] Changzhou Inst Technol, Sch Chem & Mat Sci, Changzhou 213022, Jiangsu, Peoples R China.

通讯机构：

[Chunhong Tan; Yunkai Sun; Xiao-Feng Wang] S

School of Chemistry and Chemical Engineering, University of South China, Hengyang, Hunan, P. R. China<&wdkj&>School of Chemistry and Materials Science, Changzhou Institute of Technology, Changzhou, Jiangsu, P. R. China<&wdkj&>School of Chemistry and Chemical Engineering, University of South China, Hengyang, Hunan, P. R. China<&wdkj&>State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, P. R. China

语种：

英文

期刊：

CrystEngComm

ISSN：

1466-8033

年：

2022

卷：

期：

页码：

6059-6065

DOI：

10.1039/d2ce00793b

基金类别：

This work was supported by grants from the Natural Science Foundation of Hunan Province (2021JJ30565 and 2020JJ5473) and the Science Foundation of State Key Laboratory of Structural Chemistry of CAS (20200020). We sincerely thank Prof. Tian-Lu Sheng (Fujian Institute of Research on the Structure of Matter, CAS) for his assistance in DFT calculation and crystallographic analysis. Our deepest gratitude also goes to the anonymous reviewers for their careful work and thoughtful suggestions.

机构署名：

本校为第一机构

院系归属：

化学化工学院

摘要：

The reactions of [Cu(CH3CN)(4)]ClO4 and 2-(diphenylphosphino)pyridine (dppy) with different halogen reagents NH4X (X = Cl-, Br- and l(-)) and four luminescent di-copper(i) coordination compounds, namely [Cu-2(mu-dppy)(3)Cl]ClO4 center dot H2O (1a), [Cu-2(mu-dppy)(3)Br]ClO4 (2a), Cu-2(mu-Br)(2)(mu-dppy)(eta-dppy)(2) (2b) and [Cu-2(mu-l)(2)(mu-dppy)(eta-dppy)(2)] (3b), were isolated. Intriguingly, X-ray crystallographic studies reveal that there were two kinds of Cue-core structural configuration induced by the differently sized halogen anions. With Cl--acting as a co-ligand, 1a featured a trefo...

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Halogen-induced core structural evolution of four dinuclear copper(I) luminescent coordination compounds

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