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Magnetic amino-sulfonic dual sorbent for uranyl sorption from aqueous solutions – Influence of light irradiation on sorption properties

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成果类型:
期刊论文
作者:
Hamza, Mohammed F.;Guibal, Eric;Wei, Yuezhou;Fouda, Amr
通讯作者:
Guibal, Eric(eric.guibal@mines-ales.fr);Wei, Yuezhou(yzwei@usc.edu.cn)
作者机构:
[Wei, Yuezhou; Hamza, Mohammed F.] Univ South China, Sch Nucl Sci & Technol, Hengyang 421001, Peoples R China.
[Hamza, Mohammed F.] Nucl Mat Author, POB 530, Cairo, Egypt.
[Guibal, Eric] IMT Mines Ales, Polymers Compos & Hybrids PCH, Ales, France.
[Wei, Yuezhou] Shanghai Jiao Tong Univ, Sch Nucl Sci & Engn, Shanghai, Peoples R China.
[Fouda, Amr] Al Azhar Univ, Fac Sci, Bot & Microbiol Dept, Cairo 11884, Egypt.
通讯机构:
[Guibal, E.] P
[Wei, Y.] S
Polymers Composites and Hybrids (PCH), France
School of Nuclear Science and Technology, China
语种:
英文
关键词:
An efficient magnetic composite sorbent was synthesized by incorporation of magnetite nanoparticles into polymer matrix (obtained by formaldehyde polycondensation of guanidine and amino hydroxynaphthalene sulfonic acid);Temkin equations fitted sorption isotherms while uptake kinetics are successfully modeled with the pseudo-first order rate equation;The sensitivity of uranyl ions to reduction explains the complementary metal sorption and enhanced selectivity under UV irradiation for both synthetic and complex industrial solutions;UV exposure improves the stability of sorption properties at recycling (uranium being fully desorbed using nitric acid solution);UV irradiation allows to both increase uranium sorption capacity and enhance uptake kinetics
期刊:
Chemical Engineering Journal
ISSN:
1385-8947
年:
2023
卷:
456
页码:
141099
基金类别:
Y.W acknowledges the National Natural Science Foundation of China for supporting projects [U1967218, and 11975082].
机构署名:
本校为第一机构
院系归属:
核科学技术学院
摘要:
The association of magnetite microparticles with bi-functional amino-sulfonate polymer (obtained by condensation of guanidine and amino hydroxynaphthalene sulfonic acid, mediated by formaldehyde) allows synthesizing a magnetic composite sorbent (M−GANS). The sorbent bearing both amine and sulfonate groups is efficient for uranyl sorption at pH 4–5. The sorption isotherms are successfully fitted by the Temkin equation, while kinetics is controlled by the pseudo-first order rate equation. The sorption properties are increased by UV irradiation ...

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