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A β-keto-enamine covalent organic framework fluorescent switch for selective and sensitive UO22 + detection

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成果类型:
期刊论文
作者:
Liu, Yu;Liu, Chunlin;Deng, Qiuhui;Yu, Yao;Tang, Xian;...
通讯作者:
Li, Le;Yang, Shengyuan;Zhen, DS
作者机构:
[Yang, Shengyuan; Liu, Yu; Liu, Chunlin; Li, Le; Zhen, Deshuai; Zhen, DS; Tang, Xian; Yu, Yao; Deng, Qiuhui] Univ South China, Affiliated Hosp 1, Canc Res Inst, Sch Publ Hlth,Hengyang Med Sch, Hengyang 421001, Peoples R China.
[Liu, Yu; Liu, Chunlin; Zhen, Deshuai; Yang, Shengyuan; Cai, Qingyun; Deng, Qiuhui] Hunan Univ, Sch Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Peoples R China.
[Grimes, Craig A.] Flux Photon Corp, 5950 Shiloh Rd East, Alpharetta, GA 30005 USA.
通讯机构:
[Yang, SY; Li, L; Zhen, DS ] U
Univ South China, Affiliated Hosp 1, Canc Res Inst, Sch Publ Hlth,Hengyang Med Sch, Hengyang 421001, Peoples R China.
语种:
英文
关键词:
Covalent organic frameworks;Uranyl ion;One-step condensation reaction;Density functional theory
期刊:
Sensors and Actuators B-Chemical
ISSN:
0925-4005
年:
2025
卷:
433
页码:
137564
基金类别:
CRediT authorship contribution statement Liu Yu: Writing – original draft, Investigation, Conceptualization. Liu Chunlin: Writing – original draft, Validation, Investigation, Formal analysis, Conceptualization. Deng Qiuhui: Writing – original draft, Formal analysis. Yu Yao: Methodology, Data curation. Tang Xian: Formal analysis. Li Le: Writing – review & editing, Data curation. Grimes Craig A.: Writing – review & editing. Yang Shengyuan: acquisition, Project administration. Cai Qingyun: Writing – review & editing, Project
机构署名:
本校为第一且通讯机构
院系归属:
医学院
公共卫生学院
摘要:
Nuclear accidents, uranium mining, and nuclear weapons production pose significant health and environmental concerns, and as a consequence there is ongoing interest in techniques for rapid and selective detection of the uranyl ion (UO 2 2+ ). In this study, a β-keto-enamine-linked covalent organic framework (COF) fluorescent probe was synthesized by a simple one-step condensation reaction using 1,3,5-triformylphoroglucinol (Tp) and 3,3′-dihydroxybenzidine (Db). Tp-Db exhibited a UO 2 2+ detection limit of 99.34 nM and a 10 s reaction time, ...

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