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FeP–Fe3O4 nanospheres for electrocatalytic N2 reduction to NH3 under ambient conditions

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成果类型:
期刊论文
作者:
Zhang, Huanhuan;Yan, Shuhao;Yi, Wei;Lu, Yebo;Ma, Xiao;...
通讯作者:
Yi, LH;Lu, YB;Yi, W;Wang, XZ
作者机构:
[Yi, Lanhua; Yi, LH; Bin, Yu; Zhang, Huanhuan; Ma, Xiao] Xiangtan Univ, Sch Chem, Key Lab Environmentally Friendly Chem & Applicat, Minist Educ, Xiangtan 411105, Peoples R China.
[Lu, Yebo; Lu, YB] Jiaxing Univ, Coll Informat Sci & Engn, Jiaxing 314001, Peoples R China.
[Yi, Wei; Yi, W] Minzu Normal Univ Xingyi, Sch Biol & Chem, Xingyi 562400, Peoples R China.
[Wang, Xingzhu; Wang, XZ] Univ South China, Sch Elect Engn, Hengyang 421001, Peoples R China.
[Wang, Xingzhu; Wang, XZ] Southern Univ Sci & Technol, Dept Mat Sci & Engn, Shenzhen 518055, Peoples R China.
通讯机构:
[Yi, LH ] X
[Lu, YB ] J
[Yi, W ] M
[Wang, XZ ] U
Xiangtan Univ, Sch Chem, Key Lab Environmentally Friendly Chem & Applicat, Minist Educ, Xiangtan 411105, Peoples R China.
语种:
英文
期刊:
Chemical Communications
ISSN:
1359-7345
年:
2024
卷:
60
期:
18
页码:
2528-2531
基金类别:
National Natural Science Foundation of China [52371237]; Natural Science Foundation of Hunan Province, China [2023JJ50287, 2023JJ50132]; Scientific Research Project of Colleges and Universities of the Guizhou Provincial Education Department [2022396]; Science and Technology Planning Project of the Science and Technology Bureau of Qianxinan Prefecture [2022-1-20]; Doctoral Research Start-up Fund of Minzu Normal University of Xingyi [23XYBS19]
机构署名:
本校为通讯机构
院系归属:
电气工程学院
摘要:
The electrocatalytic nitrogen reduction reaction (eNRR) under ambient conditions is deemed a promising alternative for NH(3) synthesis. In this paper, an FeP-Fe(3)O(4) nanocomposite electrocatalyst was prepared by phosphating annealing using Fe(2)O(3) as a precursor, and the resulting FeP-Fe(3)O(4) exhibited excellent N(2)-to-NH(3)-producing activity over a wide potential window. The highest faradaic efficiency of FeP-Fe(3)O(4) is 11.02% at -0.1 V vs. reversible hydrogen electrode (RHE), and the maximum NH(3) yield reaches 12.73 μg h(-1) mg(ca...

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