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A highly sensitive sensor based on a computer-designed magnetic molecularly imprinted membrane for the determination of acetaminophen

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成果类型:
期刊论文
作者:
Su, Changlin;Li, Zhiyang;Zhang, Di;Wang, Zhimei;Zhou, Xin;...
通讯作者:
Xiao, Xilin
作者机构:
[Su, Changlin; Wang, Zhimei; Xiao, Xilin; Zhou, Xin; Liao, Lifu; Li, Zhiyang; Zhang, Di] Univ South China, Hunan Prov Key Lab Design & Applicat Actinide Com, Sch Chem & Chem Engn, Hengyang City 421001, Hunan, Peoples R China.
[Xiao, Xilin] Univ South China, Sch Resource & Environm & Safety Engn, Hengyang City 421001, Hunan, Peoples R China.
[Xiao, Xilin] Hutton Univ, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China.
通讯机构:
[Xiao, Xilin] U
Univ South China, Hunan Prov Key Lab Design & Applicat Actinide Com, Sch Chem & Chem Engn, Hengyang City 421001, Hunan, Peoples R China.
语种:
英文
关键词:
Acetaminophen;Carbon paste electrode;Electrochemical sensor;Magnetic molecularly imprinted membrane
期刊:
Biosensors and Bioelectronics
ISSN:
0956-5663
年:
2020
卷:
148
页码:
111819
基金类别:
CRediT authorship contribution statement Changlin Su: Conceptualization, Writing - original draft, Writing - review & editing. Zhiyang Li: Conceptualization, Data curation, Validation, Software. Di Zhang: Conceptualization, Data curation, Formal analysis, Visualization. Zhimei Wang: Investigation, Data curation, Formal analysis. Xin Zhou: Methodology, Project administration, Resources. Lifu Liao: Conceptualization, Project administration, Resources. Xilin Xiao: Conceptualization, acquisition, Resources, Supervision.
机构署名:
本校为第一且通讯机构
院系归属:
化学化工学院
摘要:
In this paper, a sensor based on a magnetic surface molecularly imprinted membrane (MMIP) was prepared for the highly sensitive and selective determination of acetaminophen (AP). Before the experiment, the appropriate functional monomers and solvents required for the polymer were screened, and the molecular electrostatic potentials (MEPs) were calculated by the DFT/B3LYP/6-31 + G method. MMIP with high recognition of AP was synthesized based on Fe3O4@SiO2nanoparticles (NPs) with excellent core-shell structure. Next, a carbon paste electrode (CP...

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