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POSS-crosslinked poly(vinylphosphonic acid) for efficient adsorptive removal of uranium (VI) from nuclear wastewater

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成果类型:
期刊论文
作者:
Zhang, Xu;Luo, Chuanlei;Li, Hong;Liu, Renjuan;Wang, Hai;...
通讯作者:
Yue, CT
作者机构:
[Yue, Chengtao; Li, Hong; Yue, CT; Zhang, Xu; Luo, Chuanlei; Wang, Hai; Liu, Renjuan; Liu, Longcheng] Univ South China, Sch Nucl Sci & Technol, Hengyang 421001, Peoples R China.
[Yue, Chengtao; Zhang, Xu; Wang, Hai; Liu, Longcheng] Univ South China, R&D & Modelling Ctr Treatment & Disposal Radioact, Hengyang 421001, Peoples R China.
[Liu, Longcheng] Beijing Res Inst Chem Engn & Met, Beijing 101149, Peoples R China.
通讯机构:
[Yue, CT ] U
Univ South China, Sch Nucl Sci & Technol, Hengyang 421001, Peoples R China.
语种:
英文
关键词:
Poly(vinylphosphonic acid);POSS;Limited swelling capacity;Bath and column modes;Uranium (VI) removal
期刊:
Reactive and Functional Polymers
ISSN:
1381-5148
年:
2023
卷:
190
页码:
105648
基金类别:
National Natural Science Foundation of China [22202099, 12205145]; Natural Science Foun- dation of Hunan Province [2022JJ40366, 2022JJ40351, 2021JJ40457]; Excellent Youth Project of Scientific Research Fund of Hunan Provincial Education Department [19B504, 21B0440]
机构署名:
本校为第一且通讯机构
院系归属:
核科学技术学院
摘要:
Organophosphorus acid polymers with high hydrophilicity and limited swelling capacity have great application potential in disposal of uranium (VI)-containing wastewater due to its high uranium (VI) adsorption efficiency. In this work, POSS-crosslinked poly(vinylphosphonic acid) polymer is synthesized via copolymerization of octa-vinyloctasilasesquioxane and vinylphosphonic acid for uranium (VI) adsorptive removal from solution. The polymer has a high hydrophilicity and limited swelling capacity. The uranium (VI) adsorptive removal is per-formed in batch mode and the effects of polymer dosage, ...

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