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Selective Ag+Adsorption of Ureido Polymer Prepared by Cyclopolymerization Giving Large Ring Repeating Units

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成果类型:
期刊论文
作者:
Sun, Yunkai;Matsumura, Yoshimasa;Ochiai, Bungo*
通讯作者:
Ochiai, Bungo
作者机构:
[Matsumura, Yoshimasa; Ochiai, Bungo; Sun, Yunkai] Yamagata Univ, Fac Engn, Dept Chem & Chem Engn, Yamagata 9928510, Japan.
[Sun, Yunkai] Univ South China, Coll Chem & Chem Engn, Hengyang 421001, Peoples R China.
通讯机构:
[Ochiai, Bungo] Y
Yamagata Univ, Fac Engn, Dept Chem & Chem Engn, Yamagata 9928510, Japan.
语种:
英文
关键词:
cyclopolymerization;ureido polymer;selective adsorption;silver ion;large ring unit
期刊:
ACS APPLIED POLYMER MATERIALS
ISSN:
2637-6105
年:
2020
卷:
2
期:
4
页码:
1417-1421
基金类别:
This work was supported by the State Scholar Fund of China Scholarship Council (CSC, no. 201802505006). The authors thank Dr. Atsushi Sasaki of Yamagata University for his assistance with the ICP-MS measurements, Prof. Mitsumasa Kimata and Mr. Takumi Miyashita of Yamagata University for their assistance with the surface area measurement, and Mr. Wujiu Jiang of Hengyang Normal University for his assistance with the TGA measurement.
机构署名:
本校为其他机构
院系归属:
化学化工学院
摘要:
We report the synthesis of an ureido polymer containing 19-membered rings, prepared by the cyclopolymerization of a bifunctional monomer trans-1,2-bis(acryloyloxyethylureido)cyclohexane (TBAUCH) and studied for the selective adsorption of Ag+. PolyTBAUCH adsorbed Ag+ with an efficiency of 99.8%, and the maximum adsorption capacity was 39.8 mg/g. PolyTBAUCH selectively adsorbed Ag+ from an aqueous solution containing 20 different metal ions in similar concentrations. The selective adsorption depends on the controlling regioselective effect of th...

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