National Natural Science Foundation of China [11804146, 22376091]; National Natural Science Foundation of China [2020JJ5462]; Natural Science Foundation of Hunan Province
机构署名:
本校为第一且通讯机构
院系归属:
化学化工学院
摘要:
The sensitive detection of the radioactive thorium (Th) ion with an oxidation state of +4 (Th(4+)) is of great significance for environmental protection and life safety. In this study, five fluorescence sensors with regulated donor-acceptor (D-A) interactions were constructed for Th(4+) detection based on intramolecular charge transfer and aggregation-induced emission mechanisms. Among the developed sensors, TPE-D bearing electron-deficient π-bridge and weak D-A interactions presented ratiometric fluorescence detection behavior toward Th(4+) i...