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Selective Complexation and Leaching of Cobalt Using Histidine in an Alkaline Medium

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成果类型:
期刊论文
作者:
Li, Mengying;Wang, Qingliang;Guo, Weiduo;Zhao, Xu;Zhang, Yaolong;...
通讯作者:
Lei, ZW;Zhang, YH
作者机构:
[Zhou, Xiankun; Zhao, Xu; Wang, Qingliang; Lei, Zhiwu; Li, Mengying; Zhang, Yaolong] Univ South China, Sch Resource Environm & Safety Engn, Hengyang 421001, Peoples R China.
[Guo, Weiduo] Shanghai Xingzhi High Sch, Shanghai 201900, Peoples R China.
[Zhang, Yahui] Mem Univ Newfoundland, Fac Engn & Appl Sci, St John, NF A1B 3X5, Canada.
通讯机构:
[Lei, ZW ] U
[Zhang, YH ] M
Univ South China, Sch Resource Environm & Safety Engn, Hengyang 421001, Peoples R China.
Mem Univ Newfoundland, Fac Engn & Appl Sci, St John, NF A1B 3X5, Canada.
语种:
英文
关键词:
cobalt;leaching;histidine;cobalt-rich alloy slag
期刊:
Processes
ISSN:
2227-9717
年:
2025
卷:
13
期:
4
基金类别:
Research Project of Hunan Provincial Education Department of China; Hunan Students' platform for innovation and entrepreneurship training program [S202310555017, S202210555346]; [22B0440]
机构署名:
本校为第一且通讯机构
摘要:
Considering the issues of significant ammonia volatilization loss and toxic gas emission associated with the conventional ammonia leaching method used in the resource utilization of cobalt-rich alloy slag, a novel approach involving selective complexation leaching of cobalt in an alkaline histidine solution has been proposed. Under conditions of 35 degrees C temperature, a molar ratio of histidine to cobalt of 1.5, pH of 8, a leaching period of 12 h, and a stirring speed of 300 rpm, the cobalt leaching rate from cobalt-rich alloy slag exceeds 95%. In contrast, the leaching rates for impurity m...

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