Direct Electrochemical Preparation of Ni-Zr Alloy from Mixture Oxides in LiCl Molten Salt

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成果类型：

期刊论文

作者：

Ping, Xinyu;Liu, Kui;Liu, Yalan;Yuan, Liyong;Yao, Benlin;...

通讯作者：

Shi, Weiqun

作者机构：

[Yao, Benlin; Yuan, Liyong; Chai, Zhifang; Liu, Kui; Shi, Weiqun; Liu, Yalan; Ping, Xinyu] Chinese Acad Sci, Inst High Energy Phys, Lab Nucl Energy Chem, Beijing 100049, Peoples R China.

[Zhao, Xiuliang; Ping, Xinyu] Univ South China, Sch Nucl Sci & Technol, Hengyang 421000, Peoples R China.

[Yao, Benlin] China Inst Atom Energy, Dept Radiochem, Beijing 102413, Peoples R China.

[Chai, Zhifang] Soochow Univ, Sch Radiol & Interdisciplinary Sci, Suzhou 215123, Peoples R China.

通讯机构：

[Shi, Weiqun] C

Chinese Acad Sci, Inst High Energy Phys, Lab Nucl Energy Chem, Beijing 100049, Peoples R China.

语种：

英文

期刊：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY

ISSN：

0013-4651

年：

2017

卷：

164

期：

页码：

D888-D894

DOI：

10.1149/2.1361713jes

基金类别：

Science Challenge Project [JCKY2016212A504]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21577144]; Major Research Plan "Breeding and Transmutation of Nuclear Fuel in Advanced Nuclear Fission Energy System" of the Natural Science Foundation of China [91426302, 91326202]

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本校为其他机构

院系归属：

核科学技术学院

摘要：

The Ni5Zr alloy prepared from the mixture of nickel oxide (NiO) and zirconium oxide (ZrO2) powders by direct electrochemical reduction was conducted in molten lithium chloride (LiCl) at 923 K. The electrochemical reduction behaviors of ZrO2and NiO-ZrO2mixture were firstly investigated by cyclic voltammetry measurements. The influence of process parameters such as oxide composition, compression force, sintering time, and cell voltage on the electrolysis process have been comprehensively evaluated in terms of the electrochemical reducibility of ZrO2. The results demonstrated that the reduction s...

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Direct Electrochemical Preparation of Ni-Zr Alloy from Mixture Oxides in LiCl Molten Salt

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