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Difluoromethylation of: N -arylsulfonyl hydrazones with difluorocarbene leading to difluoromethyl aryl sulfones

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成果类型:
期刊论文
作者:
Zheng, Qu-Tong;Wei, Yun;Zheng, Jian;Duan, Ya-ya;Zhao, Gang;Wang, Zong-Bao;Lin, Jin-Hong*;Zheng, Xing*;Xiao, Ji-Chang*
通讯作者:
Zheng, Xing;Xiao, Ji-Chang;Lin, Jin-Hong
作者机构:
[Wang, Zong-Bao; Wei, Yun; Xiao, Ji-Chang; Zheng, Qu-Tong; Zheng, Xing] Univ South China, Inst Pharm & Pharmacol, 28 Western Changsheng Rd, Hengyang 421001, Hunan, Peoples R China.
[Wang, Zong-Bao; Wei, Yun; Xiao, Ji-Chang; Zheng, Qu-Tong; Zheng, Xing] Hunan Prov Cooperat Innovat Ctr Mol Target New Dr, 28 Western Changsheng Rd, Hengyang 421001, Hunan, Peoples R China.
[Duan, Ya-ya; Wei, Yun; Lin, Jin-Hong; Xiao, Ji-Chang; Zheng, Jian; Zheng, Qu-Tong; Lin, JH; Zhao, Gang] Univ Chinese Acad Sci, Chinese Acad Sci, Key Lab Organofluorine Chem, Shanghai Inst Organ Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China.
通讯机构:
[Zheng, X; Xiao, JC] Univ South China, Inst Pharm & Pharmacol, 28 Western Changsheng Rd, Hengyang 421001, Hunan, Peoples R China.
[Zheng, X; Xiao, JC] Hunan Prov Cooperat Innovat Ctr Mol Target New Dr, 28 Western Changsheng Rd, Hengyang 421001, Hunan, Peoples R China.
[Lin, JH; Xiao, JC] Univ Chinese Acad Sci, Chinese Acad Sci, Key Lab Organofluorine Chem, Shanghai Inst Organ Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China.
语种:
英文
期刊:
RSC Advances
ISSN:
2046-2069
年:
2016
卷:
6
期:
85
页码:
82298-82300
基金类别:
National Basic Research Program of China [2015CB931900, 2012CBA01200]; National Natural Science Foundation [21421002, 21472222, 21502214, 81273537]; Chinese Academy of Sciences [XDA02020105, XDA02020106]; Science and Technology Commission of Shanghai Municipality [15DZ1200102, 14ZR1448800]; Zhengxiang Scholar Program of the University of South China
机构署名:
本校为第一且通讯机构
院系归属:
药学与生物科学学院
摘要:
The difluoromethylation of N-arylsulfonyl hydrazones with difluorocarbene generated from difluoromethylene phosphobetaine (Ph<inf>3</inf>P<sup>+</sup>CF<inf>2</inf>CO<inf>2</inf><sup>-</sup>) to give various difluoromethyl aryl sulfones is described. &copy;2016 The Royal Society of Chemistry.

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