Difluoromethylation of N-arylsulfonyl hydrazones with difluorocarbene leading to difluoromethyl aryl sulfones

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成果类型：

期刊论文

作者：

Zheng, Qu-Tong;Wei, Yun;Zheng, Jian;Duan, Ya-ya;Zhao, Gang;...

通讯作者：

Zheng, Xing;Xiao, Ji-Chang;Lin, Jin-Hong

作者机构：

[Wang, Zong-Bao; Wei, Yun; Xiao, Ji-Chang; Zheng, Qu-Tong; Zheng, Xing] Univ South China, Inst Pharm & Pharmacol, 28 Western Changsheng Rd, Hengyang 421001, Hunan, Peoples R China.

[Wang, Zong-Bao; Wei, Yun; Xiao, Ji-Chang; Zheng, Qu-Tong; Zheng, Xing] Hunan Prov Cooperat Innovat Ctr Mol Target New Dr, 28 Western Changsheng Rd, Hengyang 421001, Hunan, Peoples R China.

[Duan, Ya-ya; Wei, Yun; Lin, Jin-Hong; Xiao, Ji-Chang; Zheng, Jian; Zheng, Qu-Tong; Lin, JH; Zhao, Gang] Univ Chinese Acad Sci, Chinese Acad Sci, Key Lab Organofluorine Chem, Shanghai Inst Organ Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China.

通讯机构：

[Zheng, X; Xiao, JC; Lin, JH] U

[Zheng, X; Xiao, JC] H

Univ South China, Inst Pharm & Pharmacol, 28 Western Changsheng Rd, Hengyang 421001, Hunan, Peoples R China.

Hunan Prov Cooperat Innovat Ctr Mol Target New Dr, 28 Western Changsheng Rd, Hengyang 421001, Hunan, Peoples R China.

Univ Chinese Acad Sci, Chinese Acad Sci, Key Lab Organofluorine Chem, Shanghai Inst Organ Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China.

语种：

英文

期刊：

RSC Advances

ISSN：

2046-2069

年：

2016

卷：

期：

页码：

82298-82300

DOI：

10.1039/c6ra20629h

基金类别：

National Basic Research Program of ChinaNational Basic Research Program of China [2015CB931900, 2012CBA01200]; National Natural Science FoundationNational Natural Science Foundation of China (NSFC) [21421002, 21472222, 21502214, 81273537]; Chinese Academy of SciencesChinese Academy of Sciences [XDA02020105, XDA02020106]; Science and Technology Commission of Shanghai MunicipalityScience & Technology Commission of Shanghai Municipality (STCSM) [15DZ1200102, 14ZR1448800]; Zhengxiang Scholar Program of the University of South China

机构署名：

本校为第一且通讯机构

院系归属：

药学与生物科学学院

摘要：

The difluoromethylation of N-arylsulfonyl hydrazones with difluorocarbene generated from difluoromethylene phosphobetaine (Ph3P+CF2CO2-) to give various difluoromethyl aryl sulfones is described. ©2016 The Royal Society of Chemistry.

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Difluoromethylation of N-arylsulfonyl hydrazones with difluorocarbene leading to difluoromethyl aryl sulfones

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