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Spectroscopic study on the reactions of bis-salophen with uranyl and then with fructose 1,6-bisphosphate and the analytical application

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成果类型:
期刊论文
作者:
Shen, Xing;Liao, Lifu*;Chen, Lin;He, Yunfei;Xu, Canhui;...
通讯作者:
Liao, Lifu
作者机构:
[Xu, Canhui; Chen, Lin; Xiao, Xilin; Liao, Lifu; Nie, Changming; Lin, Yingwu; Shen, Xing; He, Yunfei] Univ South China, Coll Chem & Chem Engn, Hengyang 421001, Hunan, Peoples R China.
通讯机构:
[Liao, Lifu] U
Univ South China, Coll Chem & Chem Engn, Hengyang 421001, Hunan, Peoples R China.
语种:
英文
关键词:
Bis-salophen;Fluorescence;Fructose 1,6-bisphosphate;Resonance light scattering;Uranyl
期刊:
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
ISSN:
1386-1425
年:
2014
卷:
123
页码:
110-116
基金类别:
National Natural Science Foundation of China (NSFC)National Natural Science Foundation of China (NSFC) [11275091, 10975069, 11275090]
机构署名:
本校为第一且通讯机构
院系归属:
化学化工学院
摘要:
The chelating reaction of bis-salophen with uranyl to form binuclear complex uranyl-bis-salophen (UBS) was studied by fluorescence spectroscopy. The coordination reaction of UBS with fructose 1,6-bisphosphate (F-1,6-BP) to form supramolecular polymer was then studied by resonance light scattering (RLS) spectroscopy. The reaction of bis-salophen with uranyl results in a remarkable enhancement of fluorescence intensity. The maximum emission wavelength of the fluorescence is at 471 nm. The reaction of UBS with F-1,6-BP results in a remarkable enhancement of RLS intensity. The maximum scattering w...

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