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A novel core–shell magnetic nano-sorbent with surface molecularly imprinted polymer coating for the selective solid phase extraction of dimetridazole

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成果类型:
期刊论文
作者:
Hu, Canhui;Deng, Jian*;Zhao, Yubao;Xia, Liangshu;Huang, Kaihui;...
通讯作者:
Deng, Jian
作者机构:
[Huang, Kaihui; Xiao, Ni; Zhao, Yubao; Hu, Canhui; Deng, Jian; Ju, Saiqin; Xia, Liangshu] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Hunan, Peoples R China.
通讯机构:
[Deng, Jian] U
Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Hunan, Peoples R China.
语种:
英文
关键词:
Dimetridazole;Magnetic nano-sorbent;Sol-gel process;Surface molecularly imprinted polymer
期刊:
Food Chemistry
ISSN:
0308-8146
年:
2014
卷:
158
页码:
366-373
基金类别:
The authors wish to thank the financial support from the Hunan Technology Department Foundation, China (No. 2013FJ3028 ) and Hunan Provincial Innovation Foundation for Postgraduate, China (No. CX2010B378 ).
机构署名:
本校为第一且通讯机构
院系归属:
化学化工学院
摘要:
A novel core-shell magnetic nano-sorbent with surface molecularly-imprinted polymer coating was prepared via a sol-gel process. Methyltrimethoxysilane and 3-aminopropyltriethoxysilane were used as functional monomers, tetraethyl orthosilicate as cross-linker, and Al3+ as dopant to generate Lewis acid sites in the silica matrix for the metal coordinate interactions with the template dimetridazole (DMZ). The ratios of the monomers, the dopant, and the cross-linker, were optimised by a OA9 (34) orthogonal array design. The resultant sorbent was characterised by scanning electron microscopy, trans...

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