Complexation and enantioselectivity of sulfur/selenium-substituted uranyl-salophens with R/S-chiral lactone for RRS/SSR-3, 5-Dimethyl-2-(3-fluorophenyl)-2-morpholinols

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作者信息关键词期刊信息基础信息归属信息摘要

成果类型：

期刊论文

作者：

Dai Linlin;Nie Changming*;Sun Weizhen;Xiao Yang;Mao Yu;...

通讯作者：

Nie Changming

作者机构：

[Nie Changming; Sun Weizhen; Xiao Xilin; Xiao Yang; Liao Lifu; Wu Zhilin; Dai Linlin; Mao Yu] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Hunan, Peoples R China.

[Nie Changming; Sun Weizhen; Xiao Xilin; Xiao Yang; Liao Lifu; Wu Zhilin; Dai Linlin; Mao Yu] Key Lab Hunan Prov Design & Applicat Nat Actinide, Hengyang 421001, Hunan, Peoples R China.

通讯机构：

[Nie Changming] U

[Nie Changming] K

Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Hunan, Peoples R China.

Key Lab Hunan Prov Design & Applicat Nat Actinide, Hengyang 421001, Hunan, Peoples R China.

语种：

英文

关键词：

3,5 dimethyl 2 (3 fluorophenyl) 2 morpholinol derivative;acetone;lactone;morpholine derivative;selenium derivative;selenium substituted uranyl salophen derivative;sulfur derivative;sulfur substituted uranyl salophen derivative;toluene;unclassified drug;water;Article;calculation;chemical structure;chirality;complex formation;density functional theory;enantiomer;enantioselectivity;vacuum

期刊：

Journal of Radioanalytical and Nuclear Chemistry

ISSN：

0236-5731

年：

2020

卷：

324

期：

页码：

993-1006

DOI：

10.1007/s10967-020-07137-1

基金类别：

We are grateful to acknowledge the support of this work from National Natural Science Foundation of China, Grant/Award Numbers: 11275090 and 11475079; Authors also greatly acknowledge the high-performance computation center (HPCC) at University of South China for computing time.

机构署名：

本校为第一且通讯机构

院系归属：

化学化工学院

摘要：

In order to explore the enantioselectivity of uranyl-salophens to chiral molecules, the newly designed receptors of Λ-type configuration sulfur/selenium-substituted uranyl-salophens with R/S-chiral δ-lactone were used to selectively coordinate and recognize a pair of enantiomers of RRS/SSR-3,5-dimethyl-2-(3-fluorophenyl)-2-morpholinols as guests based on the density functional theory calculations. The results indicated that the substituent effects of R/S-asymmetry sulfur/selenium-substituted uranyl-salophens significantly affected the structu...

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Complexation and enantioselectivity of sulfur/selenium-substituted uranyl-salophens with R/S-chiral lactone for RRS/SSR-3, 5-Dimethyl-2-(3-fluorophenyl)-2-morpholinols

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