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U(VI) capture from aqueous solution by highly porous and stable MOFs: UiO-66 and its amine derivative

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成果类型:
期刊论文
作者:
Luo, Bai-Cheng;Yuan, Li-Yong*;Chai, Zhi-Fang;Shi, Wei-Qun;Tang, Quan*
通讯作者:
Tang, Quan;Yuan, Li-Yong
作者机构:
[Luo, Bai-Cheng; Tang, Quan] Univ South China, Sch Nucl Sci & Technol, Hengyang 421001, Peoples R China.
[Luo, Bai-Cheng; Yuan, Li-Yong; Chai, Zhi-Fang; Shi, Wei-Qun] Chinese Acad Sci, Inst High Energy Phys, Lab Nucl Energy Chem, Beijing 100049, Peoples R China.
[Chai, Zhi-Fang] Soochow Univ, Sch Radiol & Interdisciplinary Sci, Suzhou 215123, Peoples R China.
通讯机构:
[Tang, Quan] U
[Yuan, Li-Yong] C
Univ South China, Sch Nucl Sci & Technol, Hengyang 421001, Peoples R China.
Chinese Acad Sci, Inst High Energy Phys, Lab Nucl Energy Chem, Beijing 100049, Peoples R China.
语种:
英文
关键词:
Metal-organic frameworks;UiO-66;Amine derivative;Uranium;Sorption
期刊:
Journal of Radioanalytical and Nuclear Chemistry
ISSN:
0236-5731
年:
2016
卷:
307
期:
1
页码:
269-276
基金类别:
Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [91426302, 21471153, 11275219, 91326202, U1432103]; Chinese Academy of SciencesChinese Academy of Sciences [XDA030104]; Priority Academic Program Development of Jiangsu Higher Education Institutions
机构署名:
本校为第一且通讯机构
院系归属:
核科学技术学院
摘要:
Metal–organic frameworks (MOFs) UiO-66 and its amine derivative (UiO-66-NH2) with high surface area and unprecedented chemical stability were synthesized and first explored for U(VI) capture from aqueous solutions. At pH 5.5, U(VI) sorption reach equilibrium in ca. 4 h and the maximum sorption capacity is more than 100 mg g−1. Moreover, they show desirable selectivity towards U(VI) over a range of competing metal ions. Sorption results demonstrate that introduction of amino groups into MOFs does not enhance U(VI) sorption, probably result fro...

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