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A novel sensor based on multi-walled carbon nanotubes and boron-doped double-layer molecularly imprinted membrane for the analysis of SCZ in pharmaceutical and biological samples

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成果类型:
期刊论文
作者:
Peng, Pengcheng;Liao, Lifu;Yu, Zhaohui;Jiang, Min;Deng, Jian;...
通讯作者:
Xiao, Xilin
作者机构:
[Peng, Pengcheng; Liao, Lifu; Jiang, Min; Deng, Jian] Univ South China, Sch Chem & Chem Engn, Key Discipline Lab Natl Def Biotechnol Uranium Mi, Hengyang City, Peoples R China
[Yu, Zhaohui; Xiao, Xilin] Univ South China, Sch Resource & Environm & Safety Engn, Hengyang City, Peoples R China
通讯机构:
[Xiao, Xilin] U
Univ South China, Sch Resource & Environm & Safety Engn, Hengyang City, Peoples R China.
语种:
英文
关键词:
Boron;Composite membranes;Density functional theory;Design for testability;Electrochemical electrodes;Electrochemical sensors;Monomers;Nanotubes;Voltammetry;Yarn;Biological samples;Differential pulse voltammetry;Molecularly imprinted;Molecularly imprinted membranes;Molecularly Imprinted Polymer;Optimal experimental conditions;Reduction peak currents;Secnidazole;Multiwalled carbon nanotubes (MWCN)
期刊:
International Journal of Environmental Analytical Chemistry
ISSN:
0306-7319
年:
2019
卷:
99
期:
15
页码:
1495-1514
基金类别:
The authors gratitude the financial support of Natural Science Foundation of China [No.31200140 and 11475079], Hunan Province Engineering Research Center of Radioactive Control Technology in Uranium Mining and Metallurgy & Hunan Province Engineering Technology Research Center of Uranium Tailings Treatment, University of South China [No. 2018YKZX1007], Innovation Foundation for Postgraduate from University of South China [No. 2018KYY048] and Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry [No. 2015jyb02].
机构署名:
本校为第一且通讯机构
院系归属:
化学化工学院
核资源工程学院
摘要:
A molecularly imprinted electrochemical sensor for the rapid detection of the anti-parasitic drug Secnidazole (SCZ) is reported. In this work, the build electrochemical sensor was based on a carbon paste electrode (CPE) modified with multi-wall carbon nanotubes (MWCNTs) and boron-embedded duplex molecularly imprinted composite membranes (B-DMICMs), that significantly increased the efficiency of the sensor for the detection of template molecule SCZ. Density functional theory (DFT) was employed to study the interactions between the template and m...

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