Synergistic cooperative effect of CF3SO2Na and bis(2-butoxyethyl)ether towards selective oxygenation of sulfides with molecular oxygen under visible-light irradiation

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成果类型：

期刊论文

作者：

Liu, Kai-Jian;Wang, Zheng;Lu, Ling-Hui;Chen, Jin-Yang;Zeng, Fei;...

通讯作者：

He, Wei-Min

作者机构：

[Zeng, Fei; Liu, Kai-Jian; Wang, Zheng; He, Wei-Min; Lu, Ling-Hui] Hunan Univ Sci & Engn, Dept Chem & Bioengn, Yongzhou 425100, Peoples R China.

[Lin, Ying-Wu; Chen, Jin-Yang] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.

[Cao, Zhong] Changsha Univ Sci & Technol, Hunan Prov Key Lab Mat Protect Elect Power & Duns, Changsha 410114, Peoples R China.

[Yu, Xianyong] Hunan Univ Sci & Technol, Sch Chem & Chem Engn, Xiangtan 411201, Peoples R China.

通讯机构：

[He, Wei-Min] H

Hunan Univ Sci & Engn, Dept Chem & Bioengn, Yongzhou 425100, Peoples R China.

语种：

英文

期刊：

Green Chemistry

ISSN：

1463-9262

年：

2021

卷：

期：

页码：

496-500

DOI：

10.1039/d0gc02663h

基金类别：

We are grateful for financial support from the Hunan Provincial Natural Science Foundation of China (No. 2019JJ40090 and 2019JJ20008).

机构署名：

本校为其他机构

院系归属：

化学化工学院

摘要：

A safe, practical and eco-friendly method for the switchable synthesis of sulfoxides and sulfones through visible-light-initiated oxygenation of sulfides at ambient temperature under transition-metal-, additives-free and minimal solvent conditions. The synergistic catalytic efforts between CF3SO2Na and 2-butoxyethyl ether represents the key promoting factor for the reaction. ...

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Synergistic cooperative effect of CF3SO2Na and bis(2-butoxyethyl)ether towards selective oxygenation of sulfides with molecular oxygen under visible-light irradiation

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