Photoredox-catalyzed unsymmetrical diamination of alkenes for access to vicinal diamines

首页 > 成果 > 详情

认领

导出

Link by DOI

反馈

作者信息关键词期刊信息基础信息归属信息摘要

成果类型：

期刊论文

作者：

Liu, Jie;Guo, Lu;Chen, Zhang;Guo, Yu*;Zhang, Wei;...

通讯作者：

Guo, Yu;Wang, Zhen;Zeng, YF;Wang, Z

作者机构：

[Liu, Jie; Wang, Zhen; Guo, Yu; Peng, Xue; Zhang, Wei; Zeng, Yao-Fu; Chen, Zhang; Guo, Y] Univ South China, Sch Pharmaceut Sci, Hengyang Med Sch, Hengyang 421001, Hunan, Peoples R China.

[Wang, Zhen] Univ South China, MOE Key Lab Rare Pediat Dis, Hengyang 421001, Hunan, Peoples R China.

[Guo, Lu] Univ South China, Nanhua Hosp, Hengyang Med Sch, Dept Sports Med, Hengyang 421001, Hunan, Peoples R China.

通讯机构：

[Wang, Z; Zeng, YF ; Wang, Z ; Guo, Y] U

Univ South China, Sch Pharmaceut Sci, Hengyang Med Sch, Hengyang 421001, Hunan, Peoples R China.

Univ South China, MOE Key Lab Rare Pediat Dis, Hengyang 421001, Hunan, Peoples R China.

语种：

英文

期刊：

Chemical Communications

ISSN：

1359-7345

年：

2024

卷：

期：

页码：

3413-3416

DOI：

10.1039/d4cc00330f

基金类别：

National Natural Science Foundation of China [22101126]; Fund of Hunan Province Cooperative Innovation Center for Molecular Target New Drug Study; Science and Technology Plan Project in Hengyang Hunan [202222035879]; Innovation and Entrepreneurship for College Students of University of South China [2022X10555171]

机构署名：

本校为第一且通讯机构

摘要：

A photoredox-catalyzed unsymmetrical diamination of alkenes by using N-aminopyridinium salts and nitriles as the amination reagents has been developed. Various vicinal diamines were obtained in moderate to excellent yields under mild reaction conditions. Furthermore, this protocol could be applied in the late-stage modification of pharmaceuticals and natural products. Preliminary mechanistic studies suggested that this methodology may undergo a radical pathway followed by a Ritter-type reaction. Unsymmetrical vicinal diamines have been achieved via the photoredox-catalyzed difunctionalization ...

反馈

产权有误：本人成果被他人认领

数据有误：数据基本信息有误

归属有误：成果的院系归属、机构署名归属有误

其他原因：

验证码：

看不清楚，换一个

确定

取消

成果认领

标题：

用户	作者	通讯作者	--
	请选择	请选择	--

确定

取消

Photoredox-catalyzed unsymmetrical diamination of alkenes for access to vicinal diamines

反馈

成果认领

提示

该栏目需要登录且有访问权限才可以访问