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Preparation and application of a carbon paste electrode modified with multi-walled carbon nanotubes and boron-embedded molecularly imprinted composite membranes

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成果类型:
期刊论文
作者:
Wang, Hongjuan;Qian, Duo;Xiao, Xilin*;Deng, Chunyan;Liao, Lifu;...
通讯作者:
Xiao, Xilin;Deng, Jian
作者机构:
[Xiao, XL; Deng, Jian; Wang, Hongjuan; Xiao, Xilin; Qian, Duo; Liao, Lifu; Lin, Ying-Wu] Univ South China, Sch Chem & Chem Engn, Key Discipline Lab Natl Def Biotechnol Uranium Mi, Hengyang 421001, Hunan, Peoples R China.
[Deng, Chunyan] Cent S Univ, Coll Chem & Chem Engn, Key Lab Resources Chem Nonferrous Met, Changsha 410083, Hunan, Peoples R China.
通讯机构:
[Xiao, XL; Deng, J] U
Univ South China, Sch Chem & Chem Engn, Key Discipline Lab Natl Def Biotechnol Uranium Mi, Hengyang 421001, Hunan, Peoples R China.
语种:
英文
关键词:
Tinidazole;Density functional theory;Multi-walled carbon nanotubes;Boron-embedded molecular imprinting composite membrane;Electrochemical sensor
期刊:
Bioelectrochemistry
ISSN:
1567-5394
年:
2018
卷:
121
页码:
115-124
基金类别:
The authors were grateful for the financial support of Hunan Technology Department Foundation , China (No. 2013FJ3028 ), Innovation Foundation for Postgraduate from University of South China (No. 2016XCX08 ), Natural Science Foundation of China [No. 31200140 and 11475079 ], and Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry [No. 2015jyb02 ].
机构署名:
本校为第一且通讯机构
院系归属:
化学化工学院
核资源工程学院
摘要:
An innovative electrochemical sensor was fabricated for the sensitive and selective determination of tinidazole (TNZ), based on a carbon paste electrode (CPE) modified with multi-walled carbon nanotubes (MWCNTs) and boron-embedded molecularly imprinted composite membranes (B-MICMs). Density functional theory (DFT) calculations were carried out to investigate the utility of template-monomer interactions to screen appropriate monomers for the rational design of B-MICMs. The distinct synergic effect of MWCNTs and B-MICMs was evidenced by the posit...

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