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MnO2 decorated Prussian blue analogues as high-performance supercapacitor electrodes

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成果类型:
期刊论文
作者:
Guo, Rongshuo;Yang, Huiyuan;Jin, Linghua;Wang, Ruibin;Zhang, Ye
通讯作者:
Linghua Jin<&wdkj&>Ye Zhang
作者机构:
[Wang, Ruibin; Guo, Rongshuo; Zhang, Ye; Jin, Linghua; Yang, Huiyuan] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China.
通讯机构:
[Linghua Jin; Ye Zhang] S
School of Chemistry and Chemical Engineering, University of South China, Hengyang 421001, China
语种:
英文
关键词:
Prussian blue analogues;MnO2;Composite materials;Microstructure;Supercapacitor
期刊:
Materials Letters
ISSN:
0167-577X
年:
2023
卷:
330
页码:
133341
基金类别:
The MnO2 nanoparticles decorated CoPBA nanocubes with excellent electrochemical performance were assembled via a simple precipitation method. The composites provide the following synergistic benefits: CoPBA allows the easy dispersion of MnO2 nanoparticles that act as the conductive building block with high specific capacitance to improve its conductivity and capacitance. Consequently, CoPBA-8MO delivers commendable specific capacitance of 945F g−1 at 1 A g−1, overwhelming pure CoPBA, MnO2 and
机构署名:
本校为第一机构
院系归属:
化学化工学院
摘要:
A composite supercapacitor electrode material, MnO2 decorated cobalt-iron Prussian blue analogue (CoPBA), has been rationally designed and fabricated through a facile precipitation method. The surface encapsulation of MnO2 onto CoPBA can result in improved electrochemical performances, because the uniformly covered MnO2 increases not only the electrical conductivity for faster ion transport but also the specific capacitance by providing more active sites. A maximum specific capacitance of 945F g(-1) at 1 A/g is observed for CoPBA@MnO2, which is 3.2-fold and 6.7-fold of those of pure CoPBA and ...

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