This work was supported by the National Natural Science Foundation of China (No: 11275090, 11475079) and the Hunan Provincial Innovation Foundation for Postgraduate (grant number CX20190712). The computational work was supported by the HPC Center of University of South China.
机构署名：
本校为第一且通讯机构
院系归属：
化学化工学院
摘要：
The design of new uranyl-ligands (uranyl-Ls) is of great significance for the separation and utilization of uranium. In this paper, the triazole group was introduced into uranyl-salophen (uranyl-S) to form new asymmetric uranyl-unilateral benzotriazole salophen (uranyl-UBS); we further replaced two oxygen atoms of uranyl-UBS with two sulfur atoms to generate uranyl-unilateral benzotriazole thio-salophen (uranyl-UBTS) as a new receptor. Then, we comprehensively explored coordination models of uranyl-UBS and uranyl-UBTS with R/S-triadimefons (R/S...
