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Novel amidoxime-functionalized covalent organic frameworks synergistically promote UO22+ removal via photocatalytic reduction and adsorption

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成果类型:
期刊论文
作者:
Liu, Yu;Deng, Qiuhui;Yu, Yao;Chen, Hong;Liu, Chunlin;...
通讯作者:
Li, Le;Zhen, DS;Cai, Qingyun
作者机构:
[Liu, Yu; Liu, Chunlin; Chen, Hong; Li, Le; Zhen, Deshuai; Yu, Yao; Deng, Qiuhui] Univ South China, Sch Publ Hlth, Hunan Key Lab Typ Environm Pollut & Hlth Hazards, Hengyang 421001, Peoples R China.
[Cai, Qingyun; Liu, Yu; Cai, QY; Zhen, Deshuai; Yu, Yao; Deng, Qiuhui] Hunan Univ, Sch Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Peoples R China.
通讯机构:
[Li, L; Zhen, DS ] U
[Cai, QY] H
Univ South China, Sch Publ Hlth, Hunan Key Lab Typ Environm Pollut & Hlth Hazards, Hengyang 421001, Peoples R China.
Hunan Univ, Sch Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Peoples R China.
语种:
英文
关键词:
Covalent organic frameworks;Uranyl ion;Adsorption;Amidoxime group;Photocatalytic reduction
期刊:
Separation and Purification Technology
ISSN:
1383-5866
年:
2025
卷:
361
页码:
131461
基金类别:
CRediT authorship contribution statement Yu Liu: Methodology, Data curation. Qiuhui Deng: Methodology, Investigation, Writing – original draft. Yao Yu: Methodology, Investigation. Hong Chen: Conceptualization, Formal analysis, Validation. Chunlin Liu: Methodology, Writing – original draft. Le Li: Data curation, Writing – review & editing. Qingyun Cai: Project administration, Writing – review & editing. Deshuai Zhen: Writing – review & editing, Supervision, acquisition.
机构署名:
本校为第一且通讯机构
院系归属:
公共卫生学院
摘要:
Efficient enrichment and recycling of uranyl ion (UO 2 2+ ) from wastewater are crucial for preventing radioactive contamination and protecting human health. Herein, two novel covalent organic frameworks (Tp-PDAN and Tp-PDAN-AO) were synthesized by a simple two-step method. Tp-PDAN-AO exhibits excellent hydrophilicity, thermal stability, and chemical stability, making it suitable for UO 2 2+ removal from acidic wastewater. The high-density amidoxime chelate groups in Tp-PDAN-AO confer high adsorption capacity and selectivity for UO 2 2+ , with ...

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