Nature Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [11375084]; Nature Science Foundation of Hunan [2017JJ4046]; Hunan Provincial Innovation Foundation For Postgraduate [CX2017B523]
机构署名:
本校为第一且通讯机构
院系归属:
化学化工学院
摘要:
Using ethylenediamine-β-cyclodextrin and α-naphthylacetic acid as raw material, a novel inclusion complex (en-β[email protected]) was synthesized. The inclusion complex structures and properties were analyzed by reliable spectroscopic and physicochemical techniques. The stoichiometry of the inclusion complex was 1:1 and the stability constant (K S ) value was found to be 2511 M −1 at 293 K. Molecular thermodynamic parameters indicated that the spontaneous and exothermic nature of the process. The inclusion form was foreseen by Chem 3D progr...