期刊论文

Wang, Xiao-Feng;Zhang, Xue-Li

英文

Journal of Molecular Structure

0022-2860

2017

1138

155-160

10.1016/j.molstruc.2017.03.007

This work was financially supported by the National Science Foundation of China (Grant No. 11375082, 11275090 and 11175080) and the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry (SRF for ROCS, SEM to Dr. X. W.).

本校为第一且通讯机构

A new polynuclear Cu(II) compound, [Cu4(bpy)4(OH)4(H2O)(BTC)]NO3·8H2O (1), was prepared by self-assembly from the solution of copper(II) nitrate and two kinds of ligands, 2,2′-bipyridine (bpy) and benzene-tricarboxylic acid (H3BTC). Single crystal structure analysis reveals that 1 features a rare asymmetric chair-like hydroxyl-bridged tetra-copper cluster: [Cu4(OH)4] core along with one H2O and one BTC3− occupied each terminal coordinated site. In addi...